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nitro-Grela-I₂ SIPr

nitro-Grela-I₂ SIPr

Chemical name:

(1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene)diiodo(2-isopropoxy-5-nitrobenzylidene)ruthenium(II)

Product number: AS2053

CAS number: 1874265-00-5

Patent number: PCT/EP2003/011222

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Description

Excellent for CM of terminal, type 1 olefins. Provides improved selectivity in metathesis of substrate bearing unprotected -OH and -COOH groups. Very good for RCM with sterically non-demanding substrates leading to small/medium rings. Less sensitive to small impurities than nitro-Grela and nitro-Grela-SIPr catalysts.

Chemical properties

Chemical formula:

C37H49I2N3O3Ru

Molecular weight:

938.68 g/mol

Physical state:

powder

Color:

olive

Handling information

High stability allows catalyst handling on air.

Storage information

Long-term storage (>1 week):

Store under inert gas in a cold place (recommended temp. 2 - 8 °C).

Short-term storage (<1 week):

Store under inert gas at ambient temperature.

Applications

Additional references

  • A. Tracz, M. Matczak, K. Urbaniak, K. Skowerski “Nitro-Grela-type complexes containing iodides – robust and selective catalysts for olefin metathesis under challenging conditions” Beilstein J. Org. Chem., 11, 1823-1832, (2015).

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