Privacy Overview

This website uses cookies, which enables the use of cookies. The cookies that are categorized as necessary are used based on the basic functionality of the functionality. We also use cookies that are used to analyze and understand how you use this website. These cookies can only be used in your application using this tool. You also have the option to allow these cookies. However, opting out of some of these cookies may be available for your browsing experience.

Catalysts

Return

FixCat

FixCat

Chemical name:

(1,3-bis(2,6-diisopropylphenyl)-4-((4-ethyl-4-methylpiperazin-1-ium-1-yl)methyl)imidazolidin-2-ylidene)dichloro(2-isopropoxybenzylidene)ruthenium(II) chloride

Product number: AS2061

CAS number: 1799947-97-9

Patent number: PCT/EP2013/053967

Ask for availability

Distributors

Description

Catalyst developed to be deposited on SBA-15. Provides high turn over numbers in heterogeneous RCM leading to small and medium rings. High stability allows realization of continuous flow process.

Chemical properties

Chemical formula:

C45H67Cl3N4ORu

Molecular weight:

887.47 g/mol

Physical state:

powder

Color:

green

Handling information

High stability allows catalyst handling on air.

Storage information

Long-term storage (>1 week):

Store under inert gas in a cold place (recommended temp. 2 - 8 °C).

Short-term storage (<1 week):

Store under inert gas at ambient temperature.

Additional references

  • T. K. Olszewski, M. Bieniek, K. Skowerski “Ruthenium-Based Complexes Bearing Quarternary Ammonium Tags as Versatile Catalysts for Olefin Metathesis: From the Discovery to Practical Applications” Org. Process Res. Dev., 24, 2, 125-145, (2020).
  • G. Szczepaniak, A. Ruszczyńska, K. Kosiński, E. Bulska, K. Grela “Highly efficient and time economical purification of olefin metathesis products from metal residues using an isocyanide scavenger” Green Chemistry, 20(6), 1280-1289, (2018).

  • H. Balcar, N. Zilkova, M. Kubu, M. Polasek, J. Zednik “Metathesis of cardanol over ammonium tagged Hoveyda-Grubbs type catalyst supported on SBA-15” Catal. Today, 304, 127-134, (2018).

  • A. Chołuj, A. Zieliński, K. Grela, M. J. Chmielewski “Metathesis@MOF: Simple and Robust Immobilization of Metathesis Catalysts inside (Al)MIL-101-NH2” ACS Catal., 6, 6343-6349, (2016).

  • K. Skowerski, J. Pastva, S. J. Czarnocki, J. Janoscova “Exceptionally Stable and Efficient Solid Supported Hoveyda-​Type Catalyst” Org. Process Res. Dev., 19, 7, 872-877, (2015).

Any questions about product?

Global
Cengiz Azap, PhD
Chief Commercial Officer
cengiz.azh780pap@apeiron-synthesis.com
Tel.: (+49) 176 8142 0090