nitro-Grela 1st gen.
Chemical name:
Dichloro(2-isopropoxy-5-nitrophenylmethylene)(tricyclohexylphosphine)ruthenium(II)
Product number: AS2080
CAS number: 625082-83-9
Patent number: PCT/EP2003/011222
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Description
Good for Enyne olefin metathesis.
Chemical properties
Chemical formula:
C28H44Cl2NO3PRu
Molecular weight:
645.60 g/mol
Physical state:
proszek
Color:
brown
Handling information
High stability allows catalyst handling on air.
Storage information
Long-term storage (>1 week):
Store under inert gas in a cold place (recommended temp. 2 - 8 °C).
Short-term storage (<1 week):
Store under inert gas at ambient temperature.
Applications
V. Sashuk, K. Grela “Synthetic and mechanistic studied on enyne metathesis: A catalyst influence” J. Mol. Catal. A Chem., 257, 59-66, (2006); B) A. Michrowska, R. Bujok, S. Harutyunyan, V. Sashuk, G. Dolgonos, K. Grela “Nitro-Substituted Hoveyda-Grubbs Ruthenium Carbenes: Enhancement of Catalyst Activity through Electronic Activation” J. Am. Chem. Soc., 126, 30, 9318-9325, (2004).
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