LatMet-SIPr
Chemical name:
(1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene)chloro(tricyclohexylphosphine)-(2-oxobenzylidene)ruthenium(II)
Product number: AS2037
CAS number: 1544328-59-7
Patent number: PCT/EP2013/065839
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Description
Latent catalyst for ROMP. Requires chemical activation (typically with in situ generated HCl). Depending on monomer purity/reactivity might require thermal activation (60 - 80 °C). Shows good solubility in dicyclopentadiene.
Chemical properties
Chemical formula:
C52H77ClN2OPRu
Molecular weight:
913.68 g/mol
Physical state:
powder
Color:
dark green
Handling information
High stability allows catalyst handling on air.
Storage information
Long-term storage (>1 week):
Store under inert gas in a cold place (recommended temp. 2 - 8 °C).
Short-term storage (<1 week):
Store under inert gas at ambient temperature.
Additional references
- A. Kozłowska, M. Dranka, M. Zachara, E. Pump, C. Slugovc, K. Skowerski, K. Grela “Chelating Ruthenium Phenolate Complexes—Synthesis, General Catalytic Activity and Applications in Olefin Metathesis Polymerization” Chem. Eur. J., 20(43), 14120 – 14125 (2014).
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Cengiz Azap, PhD
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