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Catalysts

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nitro-Grela SlPr

nitro-Grela SlPr

Chemical name:

1,3-Bis(2,6-di-i-propylphenyl)imidazolidin-2-ylidene)dichloro(2-i-propoxy-5-nitrobenzylidene)ruthenium(II)

Product number: AS2033

CAS number: 928795-51-1

Patent number: PCT/EP2003/011222

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Description

General purpose catalyst, very good for CM of terminal and disubstituted trans olefins of type 1. Very good for RCM with sterically non-demanding substrates leading to small/medium rings and for CM with electron deficient partners such as acrylates. Less sensitive to small impurities than nitro-Grela catalyst.

Chemical properties

Chemical formula:

C37H49Cl2N3O3Ru

Molecular weight:

755.78 g/mol

Physical state:

powder

Color:

green, dark green

Handling information

High stability allows catalyst handling on air.

Storage information

Long-term storage (>1 week):

Store under inert gas in a cold place (recommended temp. 2 - 8 °C).

Short-term storage (<1 week):

Store under inert gas at ambient temperature.

Applications

Apeiron’s in-house research:

Additional references

  • M. Smoleń, A. Marczyk, W. Kośnik, B. Trzaskowski, A. Kajetanowicz, K. Grela “Ruthenium-Catalysed Olefin Metathesis in Environmentally Friendly Solvents: 2-Methyltetrahydrofuran Revisited” European J. Org. Chem., 4, 640-646, (2019).
  • K. Skowerski, J. Białecki, A. Tracz, T. K. Olszewski “An attempt to provide an environmentally friendly solvent selection guide for olefin metathesis” Green Chem., 16, 1125-1130, (2013).

Any questions about product?

Global
Cengiz Azap, PhD
Chief Commercial Officer
cengiz.usrazap@apeiron-synthesis.com
Tel.: (+49) 176 8142 0090